Effect of Temperature and Composition on the FTIR Spectroscopic Properties of Barium Ferrite Compounds: Analysis of Intensity and Peak Position
DOI:
https://doi.org/10.33394/j-lkf.v14i1.19857Keywords:
Barium ferrite, FTIR spectroscopy, Peak intensity, Temperature, CompositionAbstract
This study analyzes the effect of temperature and composition on the FTIR spectroscopic properties of Barium Ferrite (BaFe) compounds, which have important applications in magnetic technology and data storage. The BaFe samples were synthesized with variations in cobalt (Co) and zinc (Zn) composition at different temperatures to examine changes in peak positions and intensities in the FTIR spectrum. The results show that the processing temperature affects the crystalline structure of BaFe, where increasing temperature leads to a decrease in the intensity of several major peaks, reflecting changes in metal-oxygen bonds and degradation of crystalline bonds. Meanwhile, variations in composition with the addition of Co and Zn increase the peak intensity in the FTIR spectrum, strengthening bond vibrations and improving material stability. This study provides important insights into how temperature and composition can influence FTIR properties in BaFe, which is relevant for applications such as permanent magnet production and magnetic data storage materials. These findings are expected to assist in the development of BaFe materials with more optimal magnetic and optical properties for various technological applications.
References
Amiri, S., & Shokrollahi, H. (2013). The role of cobalt ferrite magnetic nanoparticles in medical science. Materials Science and Engineering C, 33(1), 1-8. https://doi.org/10.1016/j.msec.2012.09.003
Angari, Y. (2011). Magnetic properties of La-substituted NiFe2O4 via egg-white precursor route. Journal of Magnetism and Magnetic Materials, 323(14), 1835-1839. https://doi.org/10.1016/j.jmmm.2011.02.003
Bhattacharya, T., Paul, A., Ray, S., Wahed, A., Ceruti, A., & Joardar, S. (2025). Antibacterial potential of nanocrystalline zinc-cobalt ferrite. Nanomaterials, 15(17), 1318. https://doi.org/10.3390/nano15171318
Devan, R., Kolekar, Y., & Chougule, B. (2006). Effect of cobalt substitution on the properties of nickel-copper ferrite. Journal of Physics Condensed Matter, 18(43), 9809-9821. https://doi.org/10.1088/0953-8984/18/43/004
Dhiman, P., Rana, G., Goyal, D., & Goyal, A. (2021). Basics of ferrites: Types and structures. In G. K. Bhargava, S. Bhardwaj, M. Singh, & K. M. Batoo (Eds.), Ferrites and multiferroics (Engineering materials). Springer. https://doi.org/10.1007/978-981-16-7454-9_1
Dippong, T., Levei, E., & Cadar, O. (2021). Recent advances in synthesis and applications of MFe2O4 (M = Co, Cu, Mn, Ni, Zn) nanoparticles. Nanomaterials, 11(6), 1560. https://doi.org/10.3390/nano11061560
Ganesh, G., Sandeep, A., Chanti, G., Bose, R., Kumar, M., Kumari, K., ... & Kumar, N. (2023). Influence of dysprosium doping on structural, magnetic, and optical properties of Ni-Zn ferrites. Physica Status Solidi (A), 220(9). https://doi.org/10.1002/pssa.202200864
Geiler, A., Yoon, S., Chen, Y., Yang, A., Chinnasamy, C., Geiler, M., ... & Vittoria, C. (2008). Alternating target laser ablation deposition of high quality barium hexaferrite thin films from barium monoferrite and hematite targets. Journal of Applied Physics, 103(7). https://doi.org/10.1063/1.2837654
Georgescu, M., López-Viota, M., Klokkenburg, M., Erné, B., Vanmaekelbergh, D., & Emmichoven, P. (2008). Short-range magnetic order in two-dimensional cobalt-ferrite nanoparticle assemblies. Physical Review B, 77(2). https://doi.org/10.1103/physrevb.77.024423
Ghzaiel, T., Dhaoui, W., Pasko, A., & Mazaleyrat, F. (2016). Effect of non-magnetic and magnetic trivalent ion substitutions on BaM-ferrite properties synthesized by hydrothermal method. Journal of Alloys and Compounds, 671, 245-253. https://doi.org/10.1016/j.jallcom.2016.02.071
Kuciakowski, J., Stępień, J., Żukrowski, J., Lachowicz, D., Żywczak, A., Gajewska, M., ... & Kmita, A. (2022). Thermal decomposition pathways of ZnxFe3-xO4 nanoparticles in different atmospheres. Industrial & Engineering Chemistry Research, 61(34), 12532-12544. https://doi.org/10.1021/acs.iecr.2c01572
Maksoud, M., Elghandour, A., El-Sayyad, G., Fahim, R., El-Hanbaly, A., Bekhit, M., ... & Awed, A. (2020). Unveiling the effect of Zn2+ substitution in enrichment of structural, magnetic, and dielectric properties of cobalt ferrite. Journal of Inorganic and Organometallic Polymers and Materials, 30(9), 3709-3721. https://doi.org/10.1007/s10904-020-01523-8
Meaz, T., & Koch, C. (2003). X-ray diffraction and Mössbauer spectroscopic study of BaCo0.5xZn0.5xTix Fe12-2xO19 (M-type hexagonal ferrite). Egyptian Journal of Solids, 26(2), 197-203. https://doi.org/10.21608/ejs.2003.150158
Melikhov, Y., Snyder, J., Jiles, D., Ring, A., Paulsen, J., Lo, C., ... & Dennis, K. (2006). Temperature dependence of magnetic anisotropy in Mn-substituted cobalt ferrite. Journal of Applied Physics, 99(8). https://doi.org/10.1063/1.2151793
Moatoshi, A., Vexler, V., & Kato, K. (2023). Structural and magnetic properties of barium ferrite with doped elements. Journal of Magnetism and Magnetic Materials, 533, 167655. https://doi.org/10.1016/j.jmmm.2023.167655
Naveen, C., Rohidas, A., Raghu, S., Havareddi, B., Ramanna, R., & Mattyappannavar, S. (2024). Synthesis and characterization of barium hexagonal ferrite (BaFe12O19). IOP Conference Series: Materials Science and Engineering, 1300(1), 012012. https://doi.org/10.1088/1757-899X/1300/1/012012
Packiaraj, G., Sakthipandi, K., & Hossain, A. (2019). Effect of 200 MeV Ag16+ swift heavy ion irradiation on structural and magnetic properties of M-type barium hexaferrite. Materials Research Express, 7(1), 016301. https://doi.org/10.1088/2053-1591/ab532d
Sehrawat, S., Saini, M., Bhankhar, A., & Shukla, R. (2022). A comparative analysis of structural, optical and electrical properties of polyaniline/ferrite (Co, Ni, Cu, Zn) composites. ECS Journal of Solid State Science and Technology, 11(11), 113005. https://doi.org/10.1149/2162-8777/ac9334
Sharma, R., Bansal, S., & Singhal, S. (2015). Tailoring the photo-Fenton activity of spinel ferrites (MFe2O4) by incorporating different cations (M = Cu, Zn, Ni and Co) in the structure. RSC Advances, 5(8), 6006-6018. https://doi.org/10.1039/c4ra13692f
Sugimoto, M. (1999). The past, present, and future of ferrites. Journal of the American Ceramic Society, 82(2), 269-280. https://doi.org/10.1111/j.1551-2916.1999.tb20058.x
Tan, G., & Chen, X. (2013). Structure and multiferroic properties of barium hexaferrite ceramics. Journal of Magnetism and Magnetic Materials, 327, 87-90. https://doi.org/10.1016/j.jmmm.2012.09.047
Ting, T., & Wu, K. (2010). Synthesis, characterization of polyaniline/BaFe12O19 composites with microwave-absorbing properties. Journal of Magnetism and Magnetic Materials, 322(15), 2160-2166. https://doi.org/10.1016/j.jmmm.2010.02.002
Waje, S., Hashim, M., Yusoff, W., & Abbas, Z. (2010). Sintering temperature dependence of room temperature magnetic and dielectric properties of Co0.5Zn0.5Fe2O4 prepared using mechanically alloyed nanoparticles. Journal of Magnetism and Magnetic Materials, 322(6), 686-691. https://doi.org/10.1016/j.jmmm.2009.10.041
Xu, P., Han, X., & Wang, M. (2007). Synthesis and magnetic properties of BaFe12O19 hexaferrite nanoparticles by a reverse microemulsion technique. The Journal of Physical Chemistry C, 111(16), 5866-5870. https://doi.org/10.1021/jp068955c
Zhao, W., Wei, P., Cheng, H., Tang, X., & Zhang, Q. (2007). FTIR spectra, lattice shrinkage, and magnetic properties of CoTi-substituted M-type barium hexaferrite nanoparticles. Journal of the American Ceramic Society, 90(7), 2095-2103. https://doi.org/10.1111/j.1551-2916.2007.01690.x
Zezyulina, P., Petrov, D., Rozanov, K., Винник, Д., Maklakov, S., Живулин, В., ... & Shannigrahi, S. (2020). Study of the static and microwave magnetic properties of nanostructured BaFe12-xTixO19. Coatings, 10(8), 789. https://doi.org/10.3390/coatings10080789
Zhou, E., Zheng, H., Zheng, L., Zheng, P., Ying, Z., Deng, J., ... & Zhou, J. (2018). Synthesis of dense, fine-grained hexagonal barium ferrite ceramics by two-step sintering process. International Journal of Applied Ceramic Technology, 15(4), 1023-1029. https://doi.org/10.1111/ijac.12864
Zhou, X., Zhou, K., Zhang, T., Fan, L., Zhang, H., & Zheng, H. (2021). Static magnetic, complex dielectric and complex permeability properties of aluminum substituted hexagonal barium ferrites based on doping concentration. Journal of the Ceramic Society of Japan, 129(9), 566-573. https://doi.org/10.2109/jcersj2.21037
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